The Effect of Carbon Nanotubes on the Conductivity and Sensitivity Properties of Polypyrrole for the Detection of NO₂ Gas

  • Isam Abbas Khudhir, Essa A.F.
Keywords: polypyrrole, MWCNTs, NO2, gas sensor, polymer conductivity

Abstract

Composite films of polypyrrole (PPy) with multi-walled carbon nanotubes (MWCNTs) were prepared for nitrogen dioxide (NO₂) gas sensor application. The fabrication process was carried out using the chemical polymerization method of pyrrole monomer with FeCl₃ and the addition of MWCNTs in 50 mL of distilled water. Next, polypyrrole (PPy) and with multi-walled carbon nanotubes (MWCNTs (nanocomposites were deposited on glass substrates and an aluminum mask was applied to the composite thin disks. The nanocomposites were characterized by scanning electron microscopy (FE-SEM) and the electrical conductivity of the nanocomposites was measured at different temperatures (RT, 100, 200 °C). The results showed an improvement in conductivity when CNTs were added to polypyrrole. The response and recovery time of the composite films in the presence of NO₂ gas was calculated by monitoring the electrical resistance at temperatures (RT, 100, 200 °C). The sensitivity of the composites to gas was also calculated, observing that the PPy/MWCNTs nanocomposite films exhibited higher sensitivity compared to pure PPy. The results show that the incorporation of multiple carbon nanotubes significantly increases the electrical conductivity and sensitivity to NO₂, highlighting the possibility of using this compound in the development of efficient gas sensors.

Author Biography

Isam Abbas Khudhir, Essa A.F.

Isam Abbas Khudhir 1, Essa A.F.2

1Department of Physics, University of Waist, College of Science isam.khudhir@uowasit.edu.iq

2University of wasit, College of science afadhel@uowasit.edu.iq

Published
2024-02-04
Section
Regular Issue